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بیست و نهمین کنفرانس شیمی آلی ایران
Intermolecular Addition of Alkenes to Aldehydes in visible-light photoredox-catalyzed radical condensation
نویسندگان :
Ali Akbari ( دانشگاه جیرفت ) , Muhammad Saleh Faryabi ( دانشگاه جیرفت )
کلید واژه ها :
benzyl alcohols،visible-light،photoredox-catalyzed
چکیده مقاله :
Alkenes are the core structure of building blocks in natural products and have found wide applications in chemical synthesis and material science [1-2]. Hence, the development of efficient methods for the functionalization of alkenes has become an important and well-studied research topic in organic synthesis. In particular, radical-mediated functionalization of alkenes has emerged as a protocol to increase molecule complexity with atom-economic efficiency, and excellent functional group tolerance [3]. we report here a new method for the addition of alkenes to aldehydes in visible-light photoredox-catalyzed in intermolecular carbon radical addition to afford benzyl alcohol derivatives (Scheme).
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