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بیست و نهمین کنفرانس شیمی آلی ایران
Design of MOF(Fe)-TUR as a new porous H-bond catalyst based on MIL-88B(Fe)-NH2 for the synthesis of new nicotinonitriles and chromeno[4,3-b]pyridines
نویسندگان :
Mahrokh Farrokh ( دانشگاه بوعلی سینا ) , Hassan Sepehrmansourie ( دانشگاه بوعلی سینا ) , Mohammad Ali Zolfigol ( دانشگاه بوعلی سینا ) , Maryam Hajjami ( دانشگاه بوعلی سینا ) , Elham Tavakoli ( دانشگاه بوعلی سینا )
کلید واژه ها :
“Anomeric effect”،“H-Bond catalyst”،“Metal-organic frameworks (MOFs)”
چکیده مقاله :
Fe-based MOFs are a class of porous materials composed of metal ions coordinated to organic ligands. Fe-based MOFs have unique advantages compared to other types of MOFs. The incorporation of iron as the metal center provides several desirable properties. Fe-based MOFs often have good thermal and chemical stability, which is very important for their practical applications [1]. H-bonded porous catalysts are catalysts that use hydrogen bonding interactions in their porous structure to carry out chemical reactions. In the field of catalysis, a porous material with hydrogen bonding capability can provide a unique environment to promote specific reactions [2]. In this regard, the goal is to create a MOF(Fe)-TUR catalyst, which turns it into a hydrogen bonding catalyst. The designed catalyst is used in the synthesis of nicotinonitriles which have biological components, and in their structure, there are indole, triazole, and nicotinonitrile, whose importance in pharmaceutical compounds has been proven [3]
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